![]() In this work, we present an adapted Born–Haber cycle for obtaining precise enthalpy values for self-assembly at the liquid–solid interface, a key ingredient for a profound thermodynamic understanding of this process. For monolayer self-assembly at the liquid–solid interface, solute molecules are initially dissolved in the liquid phase and then become incorporated into an adsorbed monolayer. The driving force for self-assembly is the associated gain in free energy with decisive contributions from both enthalpy and entropy differences between final and initial state.
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